Physical Characterization Methods for Cathode Powders

April 18, 2023

Overview

Anytime a powder is used in a process for a specific purpose, its behavior is often predicted by physical properties of the powder.  Determining the physical properties of a cathode powder can be used to decide which properties are critical to the performance of the cathode, as well as the battery in which it is used.  A sample of lithium iron phosphate (LFP) powder was characterized to determine the following physical properties:

• Specific Surface Area

• Porosity and Pore Size Distribution

• Density

• Particle Size and Size Distribution

A sample of the same batch of LFP was coated to make the surface hydrophobic using a process called Atomic Layer Deposition, and the same physical properties were determined on the coated LFP.  The difference in the physical characterization data demonstrates the sensitivity of the techniques used and aids in the detection of possible critical physical qualities required to improve cathode and battery performance.

Speaker

Tony Thornton

Tony Thornton

Senior Product Scientist Director, Product Integrity and Performance

Tony  Thornton received both his B.S. degree in Chemistry (cum laude) and his M.S. degree in Analytical Chemistry from Emory University in Atlanta, in 1980. Tony’s research at Emory involved liquid chromatography, specifically the use of ion-pair chromatography and isocratic separation of catecholamines and metabolites. His work supported early research into potential treatment of Parkinson’s disease between Emory and the Veterans Administration hospital in Atlanta.
Tony has been a key member of the Micromeritics team since 1980, specifically evolving the study of particle sizing using liquid chromatography. Tony was also instrumental in developing the SediGraph, DigiSizer, and Elzone, and has made significant contributions to development of products for particle size, physisorption, chemisorption and pycnometer product lines. Most recently, Tony was the recipient of the ASTM International 2021 Cavanaugh Award. He was recognized for outstanding promulgation of standard test methods for powder characterization and for masterful leadership in international standards development organizations.

Jack G. Saad

Jack G. Saad

Associate Scientist

Jack G. Saad earned his ACS Certified BS Chem degree in chemistry from the University of Georgia. As an undergraduate, he worked with a variety of tungsten compounds to induce photo-initiated polymerization of cyanoacrylate using specific wavelengths of visible light, an application used in the adhesive industry. He began his career at Micromeritics Instrument Corp. as a particle size analyst for their contract laboratory service where he developed protocols to obtain particle size distributions using various techniques. He spent seven years in the pharmaceutical industry in various formulation roles to include raw materials testing, manufacturing support, research and development, and quality control.He rejoined Micromeritics in 2011 in a technical and scientific support role for various characterization techniques.  He also works on collaborations with other organizations and universities to perform research support leading to publications in peer reviewed journals in various fields as well as participate in industry organizations as a subject matter expert, including the United States Pharmacopeia (USP) and the Accrediting Council for Continuing Education and Training (ACCET).

Areas of analytical expertise include: particle size, zeta potential analysis, density measurements, chromatography

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